A relaxation model for liquid-vapor phase change with metastability

نویسندگان
چکیده

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

A Relaxation Model for Liquid-vapor Phase Change with Metastability

We propose a model that describes phase transition including metastable states present in the van der Waals Equation of State. From a convex optimization problem on the Helmoltz free energy of a mixture, we deduce a dynamical system that is able to depict the mass transfer between two phases, for which equilibrium states are either metastable states, stable states or a coexistent state. The dyn...

متن کامل

Limit of metastability for liquid and vapor phases of water.

We report the limits of superheating of water and supercooling of vapor from Monte Carlo simulations using microscopic models with configurational enthalpy as the order parameter. The superheating limit is well reproduced. The vapor is predicted to undergo spinodal decomposition at a temperature of Tspvap=46±10 °C (0 °C≪Tspvap≪100 °C) under 1 atm. The water-water network begins to form at the s...

متن کامل

A Kinetic Model for Vapor-liquid Flows

The evaporation of a liquid slab into vacuum is studied by numerical solutions of the Enskog-Vlasov equation for a fluid of spherical molecules interacting by Sutherland potential. The main aim of this work is to obtain the structure of the vapor-liquid interface in non-equilibrium conditions as well as the distribution function of evaporating molecules. The results show that the distribution f...

متن کامل

Liquid Vapor Phase Transitions for Systems with Finite-Range Interactions

An outstanding problem in equilibrium statistical mechanics is to derive rigorously the existence of a liquid vapor phase transition in a continuum particle system. While such transitions are observed in all types of macroscopic systems there is at present no proof from first principles of their existence in particles interacting with any kind of reasonable potential, say Lennard Jones or hard ...

متن کامل

Nonlinear dynamics of confined thin liquid-vapor bilayer systems with phase change

We numerically investigate the nonlinear evolution of the interface of a thin liquid-vapor bilayer system confined by rigid horizontal walls from both below and above. The lateral variation of the vapor pressure arising from phase change is taken into account in the present analysis. When the liquid vapor is heated cooled and gravity acts toward the liquid, the deflection of the interface monot...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Communications in Mathematical Sciences

سال: 2016

ISSN: 1539-6746,1945-0796

DOI: 10.4310/cms.2016.v14.n8.a4